Colloid &  Nanoscience  Journal

Colloid & Nanoscience Journal

Nanostructure, surface and magnetic properties of Co-Cr alloy thin films

Document Type : Original Article

Authors
Kosar School, Department of Education and Training, District 1, Arak, Iran
Abstract
Co-Cr films were produced with electrodeposition with different pH at room temperature. The effect of electrolyte pH on the structural, surface morphology and magnetic properties of the films was studied. X-ray diffraction measurement showed that the films have hexagonal close packed structure. For the films deposited at different pH values, the surface morphologies with different-sized globular granules were observed whereas the morphology covered by uniformly distributed nanoscale grains was detected for the surfaces of all films produced from electrolytes with different Cr concentrations. Magnetic properties such as coercivity and saturation magnetization showed strong dependence on the electrolyte solution pH and consequently the crystallite size. The Co-Cr films with low Hc were achieved using relatively low electrolyte pH. The differences observed in the magnetic properties were attributed to the structural changes caused by the electrolyte pH. The Co-Cr films may have the potential applications in magnetic recording and sensors technologies.
Keywords

[1] A. Mardanifar, A. Mohseni, S. Mahdavi, Wear and corrosion of Co-Cr coatings electrodeposited from a trivalent
chromium solution: Effect of heat treatment temperature, Surface and Coatings Technology 422 (2021) 127535.
https://doi.org/10.1016/j.surfcoat.2021.127535.
[2] H-H. Sheu, C-E. Lu, H-B. Lee, N-W. Pu, P-F. Wu, S-H Hsieh M-D. Ger, Electrodeposition of black chromium–
cobalt alloy based on trivalent sulfate electrolyte, Journal of the Taiwan Institute of Chemical Engineers 59 (2016)
496-505. . https://doi.org/10.1016/j.jtice.2015.08.002.
[3] S. Surviliene, ˙ V. Jasulaitiene, ˙ A. Cesuniene, A. Lisowska-Oleksiak, The use of XPS for study of the surface
layers of Cr–Co alloy electrodeposited from Cr (III) formate–urea baths, Solid State Ionics 179 (2008) 222–227.
https://doi.org/10.1016/j.ssi.2007.12.052.
[4] S. Mahdavi , S. R. Allahkaram, Composition, characteristics and tribological behavior of Cr, Co–Cr and Co–
Cr/TiO2 nano-composite coatings electrodeposited from trivalent chromium based baths, Journal of Alloys and
Compounds 635 (2015) 150-157. https://doi.org/10.1016/j.jallcom.2015.02.119.
[5] G. Saravanan, S. Mohan, Structure, composition and corrosion resistance studies of Co–Cr alloy electrodeposited
from deep eutectic solvent (DES), J. Alloys Compd. 522 (2012) 162– 166.
https://doi.org/10.1016/j.jallcom.2012.01.140.
[6] Zhang W, Li Y, Hu S, et al. Effect of powder oxygen content on the microstructure and properties of Co– Cr dental
alloys fabricated by selective laser melting. Powder Metall. 61 (2018) 157–163.
https://doi.org/10.1080/00325899.2017.14232.
[7] Bikulčius G, Češunienė A, Selskienė A, et al. Dry sliding tribological behavior of Cr coatings electrodeposited in
trivalent chromium sulphate baths. Surf Coat
Technol.315 (2017) 130–138. https://doi.org/10.1016/j.surfcoat.2017.01.076.
[8] C.A. Huang, C.K. Lin, C.Y. Chen, Hardness variation and corrosion behavior of as-plated and annealed Cr–Ni
alloy deposits electroplated in a trivalent chromium-based bath, Surf. Coat. Technol. 203 (2009) 3686–3691.
https://doi.org/10.1016/j.surfcoat.2009.05.047.
[9] M. Nasehnejad, M. Ahmadi, Structure and size effects in the magnetic anisotropy factors of Co-Ag nano
granular films, Colloid & Nanoscience Journal 1(2023). https://doi.org/10.61186/CNJ.1.3.119.
[10] M. Boubatra, A. Azizi, G. Schmerber, A. Dinia, The influence of pH electrolyte on the electrochemical
deposition and properties of nickel thin films, Ionics 18 (2012) 425-432. https://doi.org/10.1007/s11581-011-0642-3.
[11] A. Kharmouche, S-M. Chérif, G. Schmerber, and A. Bourzami, Magnetic and structural properties of
evaporated CoxCr1− x/Si (100) and CoxCr1−x/glass thin films, Journal of magnetism and magnetic materials 310
(2007) 152-158. https://doi.org/10.1016/j.jmmm.2006.08.012.
[12] S. Mahdavi, S. R. Allahkaram, A. Heidarzadeh, and R. Tavangar, Characteristics and properties of Co–Cr alloy
coatings prepared by electrodeposition, Surface Engineering 36 (2020) 966-974.
https://doi.org/10.1080/02670844.2019.1688012.
[13] G. L. Turdean., A. Craciun, D.Popa, M. Constantiniuc. Study of electrochemical corrosion of biocompatible Co–
Cr and Ni–Cr dental alloys in artificial saliva. Influence of pH of the solution." Materials chemistry and physics 233
(2019) 390-398. https://doi.org/10.1016/j.matchemphys.2019.05.041.
[14] T. Ohgai, Y. Tanaka Y, T. Fujimaru, Soft magnetic properties of Ni–Cr and Co–Cr alloy thin films
electrodeposited from aqueous solutions containing trivalent chromium ions and glycine, Applied Electrochemical 42
(2012) 893–899. https://doi.org /10.1007/s10800-012-0472-7.
[15] S. Mahdavi, S. R. Allahkaram, Composition, characteristics and tribological behavior of Cr, Co–Cr and Co–
Cr/TiO2 nano-composite coatings electrodeposited from trivalent chromium based baths, Journal of Alloys and
Compounds 635 (2015) 150-157. https://doi.org/10.1016/j.jallcom.2015.02.119.
[16] HR. Kim, SH. Jang, Y K. Kim, JS. Son, BK. Min, KH. Kim, and TY. Kwon, Microstructures and mechanical
properties of Co-Cr dental alloys fabricated by three CAD/CAM-based processing techniques, Materials 9, (2016)
596. https://doi.org/10.3390/ma9070596.
[17] T. Koutsoukis, S. Zinelis, G. Eliades, K. Al‐Wazzan, M. Al Rifaiy, and YS. Al Jabbari, Selective laser melting
technique of Co‐Cr dental alloys: a review of structure and properties and comparative analysis with other available
techniques, Journal of Prosthodontics 24, no. 4 (2015) 303-312. https://doi.org/10.1111/jopr.12268.
[18] A. Karpuz, H. Kockar, M. Alper, Properties of electrodeposited Co–Mn films: Influence of deposition
parameters, Applied Surface Science 358 (2015) 605-611. https://doi.org/10.1016/j.apsusc.2015.08.179.
[19] H. J. Kim, K. Kim, S-R. Lee, W. Y. Jeung, Thickness dependence of (001) texture evolution and magnetic
properties of sputter-deposited FePt: MgO nanocomposite films, IEEE Transactions on Magnetics 44 (2008) 3535-
3538. https://doi.org/10.1109/TMAG.2008.2001608.
[20] A. Vicenzo, and P. L. Cavallotti, Growth modes of electrodeposited cobalt, Electrochimica Acta 49 (2004)
4079-4089. https://doi.org/10.1016/j.electacta.2004.04.001.
[21] D. H. Choi, G. H. Kim, K. H. Lee, W. Y. Jeung,Tailoring the magnetic properties of CoFePtP alloys with
variations in iron content, Journal of Magnetism and Magnetic Materials 272 (2004) E507-E508.
https://doi.org/10.1016/j.jmmm.2003.12.533.
[22] I. Z. Rahman, M. V. Khaddem-Mousavi, A. A. Gandhi, T. F. Lynch, and M. A. Rahman, Growth of
electrodeposited Ni-Co and Fe-Co magnetic films on Cu substrates,In Journal of Physics: Conference Series 61, IOP
Publishing, 2007. https://doi.org/ 10.1088/1742-6596/61/1/106.
[23] D. Jiles, Introduction to Magnetism and Magnetic Materials, Chapman and Hall, London, 1991.
Volume 2, Issue 3
Autumn 2024
Pages 328-335

  • Receive Date 31 October 2024
  • Revise Date 09 December 2024
  • Accept Date 09 December 2024