Colloid &  Nanoscience  Journal

Colloid & Nanoscience Journal

Neuro-fuzzy logic system for prediction of dye removal from aqueous solutions by a polymeric nanocomposite

Document Type : Original Article

Authors
1 Department of Physics, Qom Branch, Islamic Azad University, Qom, Iran
2 Distributed Intelligent Optimization Research Laboratory, Department of Electrical Engineering, Amirkabir University of Technology, Tehran, Iran
Abstract
Here we explain the successful synthesis of a new polymeric nanocomposite and study the removal of a cationic dye, brilliant green, from aqueous solutions. The nanocomposite is characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD). In addition, adsorption kinetics and effects of various variables such as solution pH, adsorbent mass, and initial dye concentration are investigated. Moreover, the fuzzy model is used to investigate the dye removal efficiency. The investigation of the results obtained using the fuzzy model shows that it is suitable for the prediction of dye adsorption onto nanocomposite. The coefficient of determination (R2) and mean squared error (MSE) for the optimal model were obtained to be 0.9981 and 0.1538, respectively. The equilibrium experimental data are represented by Langmuir, Freundlich, and Sips isotherms. Results briefly indicate that adsorption of dye by nanocomposite obeys Langmuir isotherm and pseudo-second-order kinetic model.
Keywords

[1] J. Zolgharnein, M. Bagtash, T. Shariatmanesh. Simultaneous removal of binary mixture of Brilliant Green and Crystal Violet using derivative spectrophotometric determination, multivariate optimization and adsorption characterization of dyes on surfactant modified nano-γ-alumina. Spectrochim Acta A. 2015; 137: 1016–1028. https://doi.org/10.1016/j.saa.2014.08.115
[2] M. Ghaedi, A. Ansari, F. Bahari, A.M. Ghaedi, A Vafaei. A hybrid artificial neural network and particle swarm optimization for prediction of removal of hazardous dye brilliant green from aqueous solution using zinc sulfide nanoparticle loaded on activated carbon.  Spectrochim Acta Part A. 2015; 137: 1004–1015. https://doi.org/10.1016/j.saa.2014.08.011
[3] V.G. Gupta, Suhas. Application of low-cost adsorbents for dye removal- A review. J Environ Manage. 2009; 90: 2013-2042. https://doi.org/10.1016/j.jenvman.2008.11.017
[4] G. Crini. Non-conventional low-cost adsorbents for dye removal: A review. Bioresour Technol. 2006; 97: 1061–1085. b https://doi.org/10.1016/j.biortech.2005.05.001
[5] J. Zolgharnein, M. Bagtash, S. Feshki, P. Zolgharnein, D. Hammond. Crossed mixture process design optimization and adsorption characterization of multi-metal (Cu(II), Zn(II) and Ni(II)) removal by modified Buxus sempervirens tree leaves. J Taiwan Inst Chem Eng. 2017 http://doi.org/10.1016/j.jtice.2017.03.020.
[6] H. Moghanian, A. Mobinikhaledi, A.G. Blackman, E. Sarough-Farahani, Sulfanilic acid-functionalized silica-coated magnetite nanoparticles as an efficient, reusable and magnetically separable catalyst for the solvent-free synthesis of 1-amido- and 1-aminoalkyl-2-naphthols. RSC Adv. 2014; 4: 28176-28185. https://doi.org/10.1039/c4ra03676j
 [7] M. Bagtash, Y. Yamini, E. Tahmasebi, J. Zolgharnein, Z. Dalirnasab, Magnetite nanoparticles coated with tannic acid as a viable sorbent for solid-phase extraction of Cd2+, Co2+ and Cr3+. Microchim Acta. 2016; 183:449–456. https://doi.org/10.1007/s00604-015-1667-5
[8] H. Moghanian, A. Mobinikhaledi, Z. Baharangiz,  Synthesis, characterization and magnetic properties of novel heat resistant polyimide nanocomposites derived from 14 Hdibenzo [a,j] xanthenes. J Polym Res. 2014; 21:513. https://doi.org/10.1007/s10965-014-0513-5
[9] A. Salabat, F. Mirhoseini, Polymer-based nanocomposites fabricated by microemulsion method, Polym. Compos. 43 (2022) 1282–94. https://doi.org/10.1002/pc.26504
[10] F. Mirhoseini, Alireza Salabat, Removal of methyl tert -butyl ether as a water pollutant by photodegradation over a new type of poly(methyl methacrylate)/TiO2 nanocomposite. Polymer Composites, 39(4) (2018) 1248–1254. https://doi.org/10.1002/pc.24059
[11] A. Salabat, F. Mirhoseini, Applications of a new type of poly(methyl methacrylate)/TiO2 nanocomposite as an antibacterial agent and a reducing photocatalyst. Photochem. Photobiol. Sci., 14(9) (2015) 1637–1643. https://doi.org/10.1039/c5pp00065c
 [12] F. Mirhoseini, Alireza Salabat, Investigation of operational parameters on the photocatalytic activity of a new type of poly(methyl methacrylate)/ionic liquid-TiO2 nanocomposite, Iranian J. Chem. Chem. Eng., 38 (2019) 101-114. https://doi.org/10.30492/IJCCE.2019.37613
[13] A. Salabat, F. Mirhoseini, F.H. Nouri, Microemulsion strategy for preparation of TiO2–Ag/poly(methyl methacrylate) nanocomposite and its photodegradation application. J. Iranian Chem. Soc. 20 (2022) 599–608. https://doi.org/10.1007/s13738-022-02693-7.
[14] F. Mirhoseini, A. Salabat, Polymer nanocomposite based composition and method for controlling water hardness, United States patent 11136247
 
[15] A. Salabat, F. Mirhoseini, M. Mahdieh, H. Saydi, A novel nanotube-shaped polypyrrole-Pd composite prepared using reverse microemulsion polymerization and its evaluation as an antibacterial agent, New J. Chem. 39 (5) (2015) 4109–4114. https://doi.org/10.1039/c5nj00175g
[16] A. Salabat, F. Mirhoseini, M. Arjomandzadegan, E. Jiryaei, A novel methodology for fabrication of Ag-polypyrrole core-shell nanosphere using microemulsion system and evaluation of its antibacterial application, New J. Chem. 41 (21) (2017) 12892–12900. https://doi.org/10.1039/c7nj00678k
[17] F. Mirhoseini, A. Salabat, Antibactrial activity based poly(methyl methacrylate) supported TiO2 photocatalyst film nanocomposite, Tech. J. Eng. Appl. Sci. 5 (2015)115-118.
[18] P. Assefi, M. Ghaedi, A. Ansari, M.H. Habibi, M.S. Momeni, Artificial neural network optimization for removal of hazardous dye Eosin Y from aqueous solution using Co2O3-NP-AC: Isotherm and kinetics study. J Ind Eng Chem. 2014; 20: 2905–2913. https://doi.org/10.1016/j.jiec.2013.11.027
[19] R. Hosseini Nia, M. Ghaedi, A.M. Ghaedi, Modeling of reactive orange 12 (RO 12) adsorption onto gold nanoparticle-activated carbon using artificial neural network optimization based on an imperialist competitive algorithm. J Mol Liq. 2014; 195: 219–229. https://doi.org/10.1016/j.molliq.2014.02.026
[20] H. Karimi, M. Ghaedi. Application of artificial neural network and genetic algorithm to modeling and optimization of removal of methylene blue using activated carbon. J Ind Eng Chem.  2014; 20: 2471–2476. https://doi.org/10.1016/j.jiec.2013.10.028
[21] A. M. Ghaedi, A. Vafaei, Applications of artificial neural networks for adsorption removal of dyes from aqueous solution: A review, Adv. Colloid Interface Sci, 2017. https://doi.org/10.1016/j.cis.2017.04.015
[22] F. Mirhoseini, A. Salabat, Ionic liquid based microemulsion method for fabrication of poly(methyl methacrylate)–TiO2 nanocomposite as highly efficient visible light photocatalyst, RSC Adv. 5 (2015) 12536–12545. https://doi.org/10.1039/c4ra14612c
[23] F. Mirhoseini, Alireza Salabat, Photocatalytic filter, United States patent 10828629.
 
 
[24] A. Zolanvari, H. Sadeghi, J. Nezamdost, K. Suratgar, High Temperature X-Ray Diffraction and Fuzzy Modeling of Ni/Cu Multilayers,  J Mater Sci Eng. 2011; 5 (4): 386.
[25] A.A. Suratgar, S.K. Nikravesh, Potential energy based stability analysis of fuzzy linguistic systems, Iranian Journal of Fuzzy Systems, 2005; 2 (1): 65-74.
[26] N.K. Kasabov, Foundation of neural networks, fuzzy systems and knowledge engineering, The MIT press, London, England, 1998.
[27] K. Samarjit, S. Das, P. Kanti Ghosh. Applications of neuro fuzzy systems: A brief review and future outline. Appl Soft Comput. 2014; 15: 243–259. https://doi.org/10.1016/j.asoc.2013.10.014
[28] S.I. Park, J.H. Lim, C.O. Kim. Surface-modified magnetic nanoparticles with lecithin for applications in biomedicine. Curr Appl Phys. 2008; 8: 706–709.  https://doi.org/10.1016/j.cap.2007.05.009
[29] F. Kamali, K. Faghihi, F. Mirhoseini, High antibacterial activity of new eco‐friendly and biocompatible polyurethane nanocomposites based on Fe3O4/Ag and starch moieties. Polym. Eng. Sci., 62(5) (2022) 1444-1462.https://doi.org/10.1002/pen.25934
[30] A. Salabat, F. Mirhoseini, R. Valirasti, Engineering poly(methyl methacrylate)/Fe2O3 hollow nanospheres composite prepared in microemulsion system as a recyclable adsorbent for removal of benzothiophene, Ind. Eng. Chem. Research 58 (2019) 17850-1785. https://doi.org/10.1021/acs.iecr.9b04322
 
 
[31] J. Zolgharnein, M. Bagtash, N. Asanjarani, Chemometrics approach for optimization of simultaneous adsorption of Alizarin red S and Congo red by cobalt hydroxide nanoparticles. J Chemometr. 2017. https://doi.org/10.1002/cem.2886
[32] M. Khajeh, A. Barkhordar, Modelling of solid-phase tea waste extraction for the removal of manganese from food samples by using artificial neural network approach, Food Chem. 2013; 141: 712–717. https://doi.org/10.1016/j.foodchem.2013.04.075
[33] J. Zolgharnein, N. Asanjrani, M. Bagtash, G. Azimi, Multi-response optimization using Taguchi design and principle component analysis for removing binary mixture of alizarin red and alizarin yellow from aqueous solution by nano γ-alumina, Spectrochim Acta A. 2014; 126: 291–300. https://doi.org/10.1016/j.saa.2014.01.100
Volume 1, Issue 3
Summer 2023
Pages 163-172

  • Receive Date 25 October 2023
  • Revise Date 09 December 2023
  • Accept Date 11 December 2023